Effects and fate of Air Pollutants: M.SC. III SEMESTER (3RD SEM) NOTES

 


Effects and fate of Air Pollutants:

There are Various Harmful Effects of the air Pollutants:

i. Carbon monoxide (source- Automobile exhaust, photochemical reactions in the atmosphere, biological oxidation by marine organisms, etc.)- Affects the respiratory activity as haemoglobin has more affinity for CO than for oxygen. Thus, CO combines with HB and thus reduces the oxygen-carrying capacity of blood. This results in blurred vision, headache, unconsciousness and death due to asphyxiation (lack of oxygen).

ii. Carbon di oxide (source- Carbon burning of fossil fuels, depletion of forests (that remove excess carbon dioxide and help in maintaining the oxygen-carbon dioxide ratio) – causes global warming.

iii. Sulphur dioxide (source- Industries, burning of fossil fuels, forest fires, electric generation plants, smelting plants, industnal boilers, petroleum refineries and volcanic eruptions)- Respiratory problems, severe headache, reduced productivity of plants, yellowing and reduced storage time for paper, yellowing and damage to limestone and marble, damage to leather, increased rate of corrosion of iron, steel, zinc and aluminium.

iv. Hydrocarbons Poly-nuclear Aromatic Compounds(PAC) and Poly-nuclear Aromatic Hydrocarbons(PAH) (source- Automobile exhaust and industries, leaking fuel tanks, leaching from toxic waste dumping sites and coal tar lining of some water supply pipes)- Carcinogenic (may cause leukaemia).

v. Chloro-fluoro carbons (CFCs) (source- Refrigerators, air conditioners, foam shaving cream, spray cans and cleaning solvents)- Destroy ozone layer which then permits harmful UV rays to enter the atmosphere. The ozone layer protects the earth from the ultraviolet rays sent down by the sun. If the ozone layer is depleted by human action, the effects on the planet could be catastrophic.

vi. Nitrogen Oxides (source- Automobile exhausts, burning of fossil fuels, forest fires, electric generation plants, smelting plants, industrial boilers, petroleum refineries and volcanic eruptions)- Forms photochemical smog, at higher concentrations causes leaf damage or affects the photosynthetic activities of plants and causes respiratory problems in mammals.

vii. Particulate matter Lead halides (lead pollution) (source- Combustion of leaded gasoline products) , Toxic effect in man.

viii. Asbestos particles (source- Mining activities) – Asbestosis – a cancerous disease of the lungs.

ix. Silicon dioxide (source- Stone cutting, pottery, glass manufacturing and cement industries) Silicosis, a cancerous disease.

x. Mercury (source- combustion of fossil fuel & plants)-brain & kidney damage.

Air pollutants affect plants by entering through stomata (leaf pores through which gases diffuse), destroy chlorophyll and affect photosynthesis. During the day time the stomata are wide open to facilitate photosynthesis. Air pollutants during day time affect plants by entering the leaf through these stomata more than night.

Pollutants also erode waxy coating of the leaves called cuticle. Cuticle prevents excessive water loss and damage from diseases, pests, drought and frost. Damage to leaf structure causes necrosis (dead areas of leaf), chlorosis (loss or reduction of chlorophyll causing yellowing of leaf) or epinasty (downward curling of leaf), and abscission (dropping of leaves).

Particulates deposited on leaves can form encrustations and plug the stomata and also reduce the availability of sunlight. The damage can result in death of the plant. S02 causes bleaching of leaves, chlorosis, injury and necrosis of leaves. N02 results in increased abscission and suppressed growth. O3 causes flecks on leaf surface, premature aging, necrosis and bleaching.

Peroxyacetyl nitrate (PAN) causes silvering of lower surface of leaf, damage to young and more sensitive leaves and suppressed growth. Fluorides cause necrosis of leaf-tip while ethylene results in epinasty, leaf abscission and dropping of flowers.

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